Influence of γ phase on the magnetostructural transition and magnetocaloric properties in Ni38Co12Mn41Sn9 melt-spun ribbons

In the present work, Ni38Co12Mn41Sn9 melt-spun ribbons were annealed under different conditions to make samples free of secondary γ phase precipitates or get them with various average grain sizes. A comparative study was carried out to demonstrate how γ phase formation affects the martensitic transf...

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Outros Autores: Chen, F., Sánchez Valdés, César Fidel, Sánchez Llamazares, J.L., Müllner, P., Tong, Y.X., Li, L.
Formato: Artículo
Idioma:English
Publicado em: 2023
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Acesso em linha:https://doi.org/10.1016/j.jmmm.2023.170900
https://www.sciencedirect.com/science/article/abs/pii/S0304885323005504?via%3Dihub
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Resumo:In the present work, Ni38Co12Mn41Sn9 melt-spun ribbons were annealed under different conditions to make samples free of secondary γ phase precipitates or get them with various average grain sizes. A comparative study was carried out to demonstrate how γ phase formation affects the martensitic transformation (MT) and the magnetocaloric properties linked to the first-order phase transition. The γ phase significantly reduces the structural transformation temperatures, while slightly increases the thermal hysteresis. The γ phase also decreases the maximum entropy change (|ΔS|max) and the effect is more significant for smaller γ phase precipitates. As compared with those with coarse γ phase grains, the ribbons containing smaller ones possess a lower |ΔS|max but a smaller maximum magnetic hysteresis loss.